Btc facile

Metal–organic framework (MOF)-based mixed matrix membranes (MMMs) were fabricated by a combination of Cu3(BTC)2 MOF and polymer cellulose acetate.
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  • Article information.
  • Facile Synthesis of Fe-based MOFs(Fe-BTC) as Efficient Adsorbent for Water Purifications?
  • A Facile Synthesis of HKUST-1 MOF through Reductive Electrosynthesis Method.

Until now, it has been a challenge to prepare lanthanide metal—organic framework films on traditional substrates, like zinc plate, indium oxide ITO , and fluorine-doped tin oxide FTO glasses in a rapid and facile method. In this paper, continuous and dense Ln-BTC MOFs films on unmodified low-cost substrates have been rapidly and easily fabricated though the newly developed electrophoretic deposition EPD method in 5 min.

Details of materials, measurement equipment, preparation, characterization of the Ln-BTC powers and films, and the fluorescence spectra of films PDF. Such files may be downloaded by article for research use if there is a public use license linked to the relevant article, that license may permit other uses. View Author Information.

Cite this: Langmuir , 33 , 50 , — Article Views Altmetric -. Citations Supporting Information. Cited By. This article is cited by 21 publications. Inorganic Chemistry , 60 2 , Chemistry of Materials , 31 24 , Inorganic Chemistry , 58 5 , Inorganic Chemistry , 57 5 , The ratiometric detection of the biomarker Ap5A for dry eye disease and physiological temperature using a rare trinuclear lanthanide metal—organic framework. Dalton Transactions , 50 8 , Facile synthesis of tunable rare earth based metal organic frameworks for enhanced fluoride retention.

Journal of Molecular Liquids , , Angewandte Chemie , 50 , Angewandte Chemie International Edition , 59 50 , Table 2 indicates that the values of R 2 increase with the increase of the values of T. According to the reference 63 , T is 0. A comparison of the maximum adsorption capacity Q m of various adsorbents is shown in Table 3. According to Table 3 , the as-synthesized HCF clearly presents higher Q m than other cellulose-based adsorbents. This increased adsorption capacity of HCF for U VI may be attributed to its fibrous structure and the addition of HST with higher specific surface area and excellent adsorption efficiency 64 in the surface of CF.

To evaluate the adsorption thermodynamic parameters, the effect of temperature on the uranium removal was investigated using 20 mL solutions containing 0.

Thermodynamic parameters i. The adsorbent reuse is an important index to further evaluate their adsorption performance and reduce the treatment cost. Then, the adsorbent was separated from the liquid by filtration and washed several times by DW to be used for the next cycle adsorption experiment.

Well-studied Cu-BTC still serves surprises: evidence for facile Cu2+/Cu+ interchange.

The reuse experiments of HCF were performed for five cycles. According to Fig. After five recycling experiments, the U VI removal percentage remained at The cotton fibre CF in this study was medical purified cotton from Xvzhou hygienic materials plant Jiangsu, China. All reagents were of analytical grade and used without further purification. The deionized water DW was used throughout the experiments. HCF was synthesized through a simple solvothermal method. In a typical synthesis of HCF, 1.

The mixture of 0.

Then, both solutions were mixed and stirred for 30 min. The resulting mixture and 0. The resultant blue fibrous products HCF were filtered in vacuum and completely washed by ethanol and DW. The morphology characteristics of the samples were obtained on a scanning electron microscope SEM Helios i, Japan. The working U VI solutions were prepared by appropriately diluting the stock solutions immediately before their use.

The adsorption capacities of U VI onto HCF and CF were investigated as a function of the solution pH, contact time, initial U concentration and temperature by batch adsorption experiments. All experiments were performed in triplicate, and the data are presented as the mean values. The dried and regenerated adsorbent was reused for further adsorption experiments, and this recycling procedure was repeated five times. The composite HCF with lower cost was fabricated via a facile solvothermal approach to adsorb U VI from aqueous solutions.

The preparation cost of the adsorbent was significantly reduced by using BA with lower cost as the ligand to replace part of the traditional ligand H 3 BTC. This work offers a new and cost-effective adsorbent HCF, which can be effectively used as a promising sorbent to remove U VI from the real multi-component U VI -containing nuclear waste influents.

Furthermore, due to the advantageous fibrous form, HCF can be easily separated from aqueous solutions, which enhances post-treatment efficiency for further practical applications. Xiong, Y. Luo, W. Engineering robust metal-phenolic network membranes for uranium extraction from seawater. Energy Environ. Liu, W. Dalton Trans. Abney, C. Materials for the recovery of uranium from seawater. Sun, Q. Bio-inspired nano-traps for uranium extraction from seawater and recovery from nuclear waste.

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A Facile Synthesis of HKUST-1 MOF through Reductive Electrosynthesis Method |

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CAS Google Scholar. The uranium recovery from aqueous solutions using amidoxime modified cellulose derivatives.

Original Research ARTICLE

Recovery of uranium by amidoximated hydroxypropyl methylcellulose. Cellulose 20 , — Anirudhan, T. Synthesis and characterization of a functionalized graft copolymer of densified cellulose for the extraction of uranium VI from aqueous solutions. A , — Adsorption and separation behavior of uranium VI by 4-vinylpyridine-grafted-vinyltriethoxysilane-cellulose ion imprinted polymer.

Uranium removal from water using cellulose triacetate membranes added with activated carbon. Isotopes 70 , — Zolfonoun, E. On-line extraction and determination of uranium in aqueous samples using multi-walled carbon nanotubes-coated cellulose acetate membrane. Lin, K. Taiwan Inst. Gu, C. Ultrasensitive non-enzymatic pesticide electrochemical sensor based on HKUSTderived copper oxide mesoporous carbon composite. Actuators B Chem. Wang, W.